JEE Main levelSingle correct optionDifficulty 2 of 3ph013
The correct order of the magnitude of electron gain enthalpy of the halogens is
AF>Cl>I>Br
BCl>Br>F>I
CCl>F>Br>I
DF>Cl>Br>I
Answer: C
The values are about Cl -349, F -333, Br -325 and I -296 kJ/mol. Fluorine falls below chlorine because of electron-electron repulsion in its small 2p subshell, giving Cl > F > Br > I.