JEE Main levelSingle correct optionDifficulty 2 of 3pn120
Among the following hydrides, the order of basic strength is
ASbHX3>AsHX3>PHX3>NHX3
BNHX3>AsHX3>PHX3>SbHX3
CPHX3>NHX3>AsHX3>SbHX3
DNHX3>PHX3>AsHX3>SbHX3
Answer: D
As the central atom becomes larger, the lone pair is spread over a larger volume and its availability for donation decreases. Basic strength therefore falls from NH3 to SbH3.