JEE Main levelSingle correct optionDifficulty 2 of 3pn118
The correct order of boiling points of the hydrides of group 16 is
AHX2Te>HX2O>HX2Se>HX2S
BHX2O>HX2Te>HX2Se>HX2S
CHX2Te>HX2Se>HX2S>HX2O
DHX2O>HX2S>HX2Se>HX2Te
Answer: B
H2O is exceptionally high because of extensive hydrogen bonding. Among the rest, van der Waals forces increase with molar mass, so H2Te > H2Se > H2S. The full order is H2O > H2Te > H2Se > H2S.