JEE Advanced levelSingle correct optionDifficulty 3 of 3pb201
8.96 L (at STP) of a CO and COX2 mixture has an average molar mass of 36 g/mol. It is bubbled through excess lime water. Taking molar volume 22.4 L/mol and C = 12, O = 16, Ca = 40, the mass of CaCOX3 precipitated is
A10.0 g
B20.0 g
C40.0 g
D8.8 g
Answer: B
Total moles = 8.96/22.4 = 0.4. Let the mole fraction of CO be x: 28x + 44(1 - x) = 36, so x = 0.5. COX2 = 0.2 mol. CO does not react with lime water, and each COX2 gives one CaCOX3 (100 g/mol), so mass = 0.2 x 100 = 20.0 g.