JEE Main levelSingle correct optionDifficulty 2 of 3pb061
Carbon monoxide forms stable metal carbonyls such as Ni(CO)X4 mainly because CO
Adonates a lone pair on oxygen to the metal and accepts no electron density back
Btransfers one electron to the metal to form an ionic NiX+ complex
Cis a pure π donor through its filled π bonding orbitals
Ddonates a lone pair on carbon to the metal and accepts metal d electrons into its empty π∗ orbitals
Answer: D
Carbonyl bonding is synergic. CO uses the lone pair on carbon for a sigma bond to the metal, and the metal back-donates d electrons into the empty π∗ orbitals of CO. This back-bonding strengthens the metal-carbon bond.