JEE Main levelSingle correct optionDifficulty 2 of 3pb136
In the Hall-Heroult process, cryolite NaX3AlFX6 is added to
Areduce AlX2OX3 chemically to Al
Boxidise the carbon anode
Clower the melting point of the mixture and increase its electrical conductivity
Draise the operating temperature to above 2000 K
Answer: C
Pure AlX2OX3 melts near 2300 K and conducts poorly. Dissolving it in molten cryolite (with CaFX2) lowers the electrolysis temperature to about 1200 K and makes the melt conducting.