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JEE Advanced levelSingle correct optionDifficulty 3 of 3pb122

Assertion (A): is less stable than and decomposes on gentle heating to and . Reason (R): The electrons of Pb are held tightly (inert pair effect), so the +2 state is favoured over +4.

  1. ABoth A and R are true and R is the correct explanation of A
  2. BBoth A and R are true but R is not the correct explanation of A
  3. CA is true but R is false
  4. DA is false but R is true

Answer: A

A is true: . R is true and is exactly the reason, since Pb(IV) needs the unwilling pair to participate and is therefore a strong oxidant that reverts to Pb(II).
Practice p-Block Elements: Groups 13 and 14 More on Trends in group 13 and group 14

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