JEE Advanced levelOne or more correct optionsDifficulty 3 of 3pb109
Which of the following statements about tin and lead metals and their hydroxides are correct?
ATin dissolves in hot concentrated HCl to give SnClX2 and HX2.
BLead is attacked only superficially by dilute HCl and dilute HX2SOX4 because an insoluble PbClX2 or PbSOX4 film forms.
CGaseous SnClX2 is a linear molecule.
DPb(OH)X2 dissolves in excess NaOH to give a plumbite.
Answer: A, B, D
Tin is above hydrogen in the electrochemical series and gives SnClX2+HX2 with hot conc. HCl. The insoluble surface film protects lead. Gaseous SnClX2 has a lone pair on Sn (sp2-like, bent), so it is not linear. Pb(OH)X2+2NaOHNaX2PbOX2+2HX2O, which shows amphoteric character. Statements 1, 2 and 4 are correct.