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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3pb106

Which of the following are consequences of, or correctly explained by, the inert pair effect in group 14?

  1. APb(IV) compounds are strong oxidising agents.
  2. B is less stable than in compounds.
  3. C is a stronger oxidising agent than .
  4. D does not exist at ordinary conditions as Pb(IV) oxidises .

Answer: A, D

Reluctance of the pair to bond makes Pb(II) more stable than Pb(IV), so Pb(IV) compounds readily oxidise others. That is why oxidises and cannot exist. Statements 2 and 3 reverse the trends: Sn(IV) is stable and a poor oxidiser. Statements 1 and 4 are correct.
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