JEE Main levelSingle correct optionDifficulty 2 of 3pb082
Assertion (A): SiClX4 is readily hydrolysed by water whereas CClX4 is not.
Reason (R): Silicon has vacant d orbitals that can accept a lone pair from water, but carbon has none.
ABoth A and R are true and R is the correct explanation of A
BBoth A and R are true but R is not the correct explanation of A
CA is true but R is false
DA is false but R is true
Answer: A
SiClX4+4HX2OSi(OH)X4+4HCl occurs readily, but CClX4 is inert to water, so A is true. Carbon in period 2 cannot expand its octet, while silicon can accept the lone pair of water into a 3d orbital (the standard explanation). So R is true and explains A.