JEE Advanced levelOne or more correct optionsDifficulty 3 of 3pb053
Select the correct statement(s) about potash alum, KAl(SOX4)X2⋅12HX2O.
AIts aqueous solution is acidic.
BIts solution gives a white precipitate with BaClX2 that is insoluble in dilute HCl.
CIt is used as a coagulant in water purification.
DIt is a complex salt and its solution does not give the tests of KX+ or AlX3+ ions.
Answer: A, B, C
Hydrolysis of [Al(HX2O)X6]X3+ makes the solution acidic, so A is true. The gelatinous Al(OH)X3 formed adsorbs and coagulates suspended impurities, so B is true. BaX2++SOX4X2−BaSOX4, which is insoluble in dilute acid, so C is true. An alum is a double salt that dissociates completely in water and shows the tests of all its ions, so D is false.