JEE Advanced levelSingle correct optionDifficulty 3 of 3pb046
A thermite mixture contains 13.5g of Al powder and 64g of FeX2OX3, and reacts according to the equation 2Al+FeX2OX3AlX2OX3+2Fe. Taking Al=27, Fe=56, O=16, the mass of iron formed when the limiting reagent is fully consumed is
A14.0g
B22.4g
C28.0g
D44.8g
Answer: C
n(Al)=13.5/27=0.50mol; n(FeX2OX3)=64/160=0.40mol, which would need 0.80mol Al. So Al is the limiting reagent. 2mol Al give 2mol Fe, so 0.50mol Fe =0.50×56=28.0g. (Using FeX2OX3 would wrongly give 44.8g.)