JEE Advanced levelSingle correct optionDifficulty 3 of 3pb037
Hydrolysis and condensation of a mixture of 18mol of (CHX3)X2SiClX2 and 4mol of (CHX3)X3SiCl gives only linear silicone molecules of the type (CHX3)X3Si−[O−Si(CHX3)X2]Xn−O−Si(CHX3)X3, all with the same chain length. The value of n is
A18
B4
C9
D4.5
Answer: C
(CHX3)X3SiCl has one Cl, so it caps a chain end; each chain needs two caps. 4mol of capping reagent gives 4/2=2mol of chains. The 18mol of difunctional (CHX3)X2SiClX2 is shared among these 2 chains, so n=18/2=9.