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JEE Advanced levelSingle correct optionDifficulty 3 of 3pb036

Consider these statements: (i) germanium is a metalloid; (ii) tin shows allotropy (grey and white forms); (iii) the +4 state is more stable than the +2 state for lead; (iv) is readily hydrolysed but is not; (v) like , solid has a giant covalent network. The number of correct statements is

  1. AFive
  2. BTwo
  3. CThree
  4. DFour

Answer: C

(i) true: Ge is a metalloid. (ii) true: grey (alpha) and white (beta) tin. (iii) false: because of the inert pair effect Pb(II) is more stable. (iv) true: Si can use vacant orbitals (or expand its coordination) to accept water, whereas C cannot. (v) false: solid is a molecular solid. Hence three are correct: (i), (ii) and (iv).
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