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JEE Main levelSingle correct optionDifficulty 2 of 3pb012

The first ionisation enthalpy of gallium is slightly higher than that of aluminium, although Ga lies below Al. The best reason is

  1. Athe lanthanide contraction operates between Al and Ga
  2. Bgallium has a larger atomic radius than aluminium
  3. Cthe inert pair effect makes gallium more stable as
  4. Dthe ten electrons shield the nuclear charge poorly, so the effective nuclear charge on the electron is higher

Answer: D

Between Al and Ga the subshell is filled. These electrons shield poorly, so the nuclear charge is felt more strongly by the electron of Ga and its radius is not much larger than Al. This keeps the ionisation enthalpy from falling. Lanthanide contraction only comes much later (after filling).
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