JEE Main levelSingle correct optionDifficulty 2 of 3o4196
1,1-Dibromopropane is heated with excess NaNHX2 (3 equivalents) and the mixture is then treated with water. The product is:
Apropene
Bpropane
Cpropyne
Dpropan-1-ol
Answer: C
A geminal dihalide loses two molecules of HBr with NaNHX2 to give a terminal alkyne. The third equivalent deprotonates it to sodium propynide, CHX3C≡CNa, and water then regenerates propyne, CHX3C≡CH.