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In an E2 elimination from an acyclic alkyl halide, the preferred spatial arrangement of the beta C-H bond and the C-X bond is:

  1. Asyn-periplanar (dihedral angle )
  2. Banti-periplanar (dihedral angle )
  3. Cgauche (dihedral angle )
  4. Dperpendicular (dihedral angle )

Answer: B

The E2 transition state needs the C-H bond being broken and the C-X bond to lie in one plane so that the p orbitals of the new pi bond overlap well. The staggered anti-periplanar arrangement () is lowest in energy and is preferred. Syn elimination () is eclipsed and seen only in rigid systems.
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