Answer: A
The ratio is 4.02×10−4/6.0×10−5=6.7, a large primary kinetic isotope effect. A C-H bond (not C-Br alone) is therefore broken in the rate-determining step. With second-order kinetics and a secondary halide without acidic hydrogens, this is the concerted E2 mechanism. In E1 the isotope effect would be close to 1.