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In the E1 mechanism, the slowest (rate-determining) step is

  1. Aremoval of a beta-hydrogen by the base
  2. Bionisation of the substrate to give a carbocation
  3. Csimultaneous removal of a beta-hydrogen and the leaving group
  4. Dattack of the nucleophile on the carbocation

Answer: B

In E1 the substrate first ionises to a carbocation and a leaving group; this heterolysis has the highest barrier. Loss of the beta-proton to the solvent from the carbocation is fast.
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