JEE Main levelSingle correct optionDifficulty 2 of 3o2252
Take the relative reactivities per hydrogen for ClX2 at 25 ∘C as primary : secondary : tertiary = 1 : 3.8 : 5. The alkane shown is monochlorinated at 25 ∘C. What percentage of the product is the secondary chloride (to the nearest whole number)?
A33%
B44%
C56%
D76%
Answer: C
The alkane is propane. Primary: 6×1=6; secondary: 2×3.8=7.6. The 2-chloropropane share is 7.6/13.6=55.9%, about 56%.