MolSynapsequestion bank
MolSynapse / Question bank / Organic Reaction Mechanisms II: Electrophilic and Radical Reactions / Electrophilic aromatic substitution: mechanism and directing effects
JEE Main levelSingle correct optionDifficulty 2 of 3o2133

Assertion (A): Nitrobenzene does not undergo Friedel-Crafts reaction. Reason (R): The group strongly deactivates the benzene ring towards electrophilic attack.

  1. ABoth A and R are true and R is the correct explanation of A
  2. BBoth A and R are true but R is not the correct explanation of A
  3. CA is true but R is false
  4. DA is false but R is true

Answer: A

Friedel-Crafts reactions need a fairly electron-rich ring because the electrophile is only a carbocation or acylium ion. The group withdraws electrons by -I and -M effects and makes the ring too unreactive. A and R are both true and R explains A.
Practice Organic Reaction Mechanisms II: Electrophilic and Radical Reactions More on Electrophilic aromatic substitution: mechanism and directing effects

More questions on Electrophilic aromatic substitution: mechanism and directing effects