JEE Main levelOne or more correct optionsDifficulty 2 of 3o2032
Which reagent combinations convert propene mainly into propan-2-ol?
Adilute HX2SOX4, then warm water
BHg(OAc)X2/HX2O, then NaBHX4
CBHX3⋅THF, then HX2OX2/NaOH
DHBr with peroxide, then aqueous KOH
Answer: A, B
Acid hydration and oxymercuration-demercuration are both Markovnikov and give propan-2-ol. Hydroboration-oxidation gives propan-1-ol. HBr with peroxide gives 1-bromopropane, which with aqueous KOH gives propan-1-ol.