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Organic Reaction Mechanisms II: Electrophilic and Radical Reactions
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Electrophilic addition to alkenes and Markovnikov rule
NEET level
Single correct option
Difficulty 1 of 3
o2011
The intermediate formed in the first (slow) step of the addition of HBr to propene in the dark is
A
a carbene
B
a carbanion
C
a carbocation
D
a free radical
Answer: C
The
π
bond attacks H
+
of HBr in the slow step, giving the isopropyl carbocation and
Br
X
−
. The carbocation is then captured by bromide in a fast step.
Practice Organic Reaction Mechanisms II: Electrophilic and Radical Reactions
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