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NEET levelSingle correct optionDifficulty 1 of 3o1221

The ketone shown is treated with an excess of methylmagnesium bromide in dry ether, followed by aqueous acid work-up. To which class does the product belong?

  1. AHemiketal
  2. BPrimary alcohol
  3. CSecondary alcohol
  4. DTertiary alcohol

Answer: D

Propanone (acetone) is a ketone, so one methyl group adds to the carbonyl carbon and gives a tertiary alkoxide. Protonation on work-up gives 2-methylpropan-2-ol, a tertiary alcohol (aldehydes give secondary alcohols, formaldehyde gives primary).
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