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JEE Advanced levelSingle correct optionDifficulty 3 of 3o1149

Consider the carbonyl compounds I , II , III and IV . The correct order of decreasing rate of addition of is

  1. AI > II > III > IV
  2. BII > I > III > IV
  3. CI > II > IV > III
  4. DIII > II > I > IV

Answer: A

The nitro group (strong -M, -I) makes the carbonyl carbon most electrophilic. Benzaldehyde has no donor. The methoxy group donates by +M and lowers reactivity in III. IV combines this +M donation with the extra methyl group, which reduces electrophilicity and increases hindrance, so it is the slowest.
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