JEE Main levelSingle correct optionDifficulty 2 of 3o1125
Phenylmagnesium bromide in ether is treated with solid COX2 and then with HX3OX+. The product is
Abenzaldehyde
Bbenzyl alcohol
Cbenzoic acid
Dphenylacetic acid
Answer: C
The carbanion-like carbon of CX6HX5MgBr attacks the carbon of COX2 to give CX6HX5COOMgBr, and acidification gives CX6HX5COOH. The carbon count increases by one and the product is a carboxylic acid, not an aldehyde or alcohol.