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Organic Reaction Mechanisms I: Nucleophiles and Carbonyl Addition
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Addition of cyanide, bisulphite, Grignard reagents
JEE Main level
Single correct option
Difficulty 2 of 3
o1123
Benzaldehyde is treated with (i)
HCN
, trace
KCN
; (ii)
H
X
3
O
X
+
, heat. The final organic product is
A
2-hydroxy-2-phenylethanoic acid (mandelic acid)
B
benzoic acid
C
2-phenylethanoic acid
D
benzyl alcohol
Answer: A
Step (i) gives
C
X
6
H
X
5
−
CH
(
OH
)
−
CN
. Acid hydrolysis converts the nitrile
−
CN
into
−
COOH
and leaves the OH untouched, giving
C
X
6
H
X
5
−
CH
(
OH
)
−
COOH
, mandelic acid.
Practice Organic Reaction Mechanisms I: Nucleophiles and Carbonyl Addition
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