NEET levelSingle correct optionDifficulty 1 of 3o1112
In the addition of HCN to a ketone, a small amount of KCN or NaOH is added mainly because it
Aconverts the carbonyl oxygen into a better leaving group
Braises the concentration of the nucleophile CNX−
Cforms an enolate of the ketone
Dreduces the carbonyl group to an alcohol
Answer: B
HCN is a weak acid (pKa about 9.2), so pure HCN supplies very little CNX−. Base shifts HCNHX++CNX− to the right, and CNX− is the attacking nucleophile.