NEET levelSingle correct optionDifficulty 1 of 3o1111
Acetaldehyde, CHX3−CHO, is treated with HCN in the presence of a trace of base. The product is
A2-hydroxypropanenitrile
B3-hydroxypropanenitrile
Cpropanenitrile
D2-hydroxypropanoic acid
Answer: A
Cyanide ion adds to the carbonyl carbon and the alkoxide is protonated by HCN. This gives the cyanohydrin CHX3−CH(OH)−CN, i.e. 2-hydroxypropanenitrile. Hydrolysis to the acid would need a separate aqueous acid step.