NEET levelSingle correct optionDifficulty 1 of 3o1065
Acetaldehyde is warmed with excess methanol containing a little dry HCl gas. The product is
ACHX3−CO−OCHX3
BCHX3−CHX2−OCHX3
CCHX3−CH(OH)OCHX3
DCHX3−CH(OCHX3)X2
Answer: D
Dry acid catalyses addition of two molecules of methanol to the aldehyde; the first gives the hemiacetal and the second replaces the OH, giving the acetal CHX3CH(OCHX3)X2 (1,1-dimethoxyethane). The hemiacetal is only an intermediate.