NEET levelSingle correct optionDifficulty 1 of 3o1064
Which of the following does NOT form a crystalline bisulphite addition product with saturated aqueous NaHSOX3?
Aacetaldehyde
Bcyclohexanone
Cacetophenone, CX6HX5−CO−CHX3
Dacetone
Answer: C
Aldehydes, methyl ketones and unhindered cyclic ketones add bisulphite. Acetophenone is conjugated with the ring and hindered by the phenyl group, so it does not give an appreciable adduct.