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JEE Main levelSingle correct optionDifficulty 2 of 3nc239

The diamide shown is subjected to Hofmann bromamide degradation (excess /). Which structure is the product?

  1. AStructure A
  2. BStructure B
  3. CStructure C
  4. DStructure D

Answer: A

The compound shown is adipamide (hexanediamide). Each of the two groups loses its carbonyl carbon, giving a diamine with two fewer carbons: six carbons become four, i.e. butane-1,4-diamine.
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