JEE Main levelSingle correct optionDifficulty 2 of 3nc042
When aniline is heated with CHClX3 and ethanolic KOH, the foul-smelling product is:
Abenzaldehyde, CX6HX5CHO
Bphenyl isocyanide, CX6HX5NC
Cphenyl isocyanate, CX6HX5NCO
Dbenzonitrile, CX6HX5CN
Answer: B
The base converts chloroform into dichlorocarbene, which is attacked by the primary amine and, after loss of two molecules of HCl, gives the isocyanide RNC. Here R is phenyl, so the product is phenyl isocyanide, not the nitrile.