MolSynapsequestion bank
MolSynapse / Question bank / Amines and Aromatic Nitrogen Compounds / Reactions of amines: acylation, carbylamine, Hinsberg test
JEE Main levelSingle correct optionDifficulty 2 of 3nc042

When aniline is heated with and ethanolic , the foul-smelling product is:

  1. Abenzaldehyde,
  2. Bphenyl isocyanide,
  3. Cphenyl isocyanate,
  4. Dbenzonitrile,

Answer: B

The base converts chloroform into dichlorocarbene, which is attacked by the primary amine and, after loss of two molecules of HCl, gives the isocyanide . Here is phenyl, so the product is phenyl isocyanide, not the nitrile.
Practice Amines and Aromatic Nitrogen Compounds More on Reactions of amines: acylation, carbylamine, Hinsberg test

More questions on Reactions of amines: acylation, carbylamine, Hinsberg test