JEE Advanced levelNumerical answerDifficulty 3 of 3mc015
Element X has two isotopes, of atomic masses 69 and 71, and its average atomic mass is 69.8. What mass (in g) of the heavier isotope is present in a 34.9g sample of the element? Give the answer to one decimal place.
Numerical answer type, answer in g, tolerance 0.05.
Answer: 14.2 g
Let the atom fraction of the isotope of mass 71 be f: 69(1−f)+71f=69.8, so f=0.40. Moles of atoms =34.9/69.8=0.50. Heavy atoms =0.40×0.50=0.20 mol, mass =0.20×71=14.2g.