JEE Advanced levelOne or more correct optionsDifficulty 3 of 3mt092
Which of the following thermite-type reductions are thermodynamically possible with the metal as reductant (Al lies below Cr, Fe and Cu on the Ellingham diagram, and Cr lies below Fe)?
AAlX2OX3 reduced by Fe
BCrX2OX3 reduced by Al
CFeX2OX3 reduced by Al
DAlX2OX3 reduced by Cr
Answer: B, C
A metal whose oxide line is lower reduces the oxide of a metal whose line is higher. Al reduces FeX2OX3 and CrX2OX3. The reverse reductions of AlX2OX3 by Fe or Cr would have positive ΔG∘.