JEE Advanced levelOne or more correct optionsDifficulty 3 of 3mt090
Choose the correct statements about the Ellingham diagram for oxides (standard Gibbs energy per mole of OX2 against temperature).
ALines for most metal oxide formations slope upward because gaseous OX2 is consumed.
BThe line for 2CO+OX22COX2 has a positive slope.
CBelow about 983 K, carbon is thermodynamically a better reducing agent than CO.
DThe line for 2C+OX22CO has a negative slope.
Answer: A, B, D
The 2C+OX22CO line falls because gas moles increase, and the 2CO+OX22COX2 line rises because gas moles decrease. Metal oxide formation consumes OX2, so ΔS∘<0 and the line rises. Below about 983 K the CO line is lower than the carbon-to-CO line, so CO is the better reductant there and the fourth statement is false.