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JEE Main levelSingle correct optionDifficulty 2 of 3mt072

Sulphide ores are generally roasted to oxides before reduction with carbon mainly because

  1. Athe sulphide is more volatile than the oxide
  2. Bcarbon reacts only with sulphur dioxide
  3. Creduction of the oxide by carbon is thermodynamically feasible whereas direct reduction of the sulphide is not
  4. Droasting makes the ore magnetic

Answer: C

The Gibbs energy of formation of is positive and most metal sulphides are not stable enough for carbon to reduce them. So the sulphide is converted to the oxide, which carbon can reduce at a suitable temperature.
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