JEE Main levelSingle correct optionDifficulty 2 of 3mt019
On an Ellingham diagram of ΔG∘ against T, which of the following lines has a negative slope?
A34Al+OX232AlX2OX3
BC+OX2COX2
C2C+OX22CO
D2Mg+OX22MgO
Answer: C
The slope equals −ΔS∘. Forming 2 mol of CO gas from 1 mol of OX2 increases the amount of gas, so ΔS∘>0 and the slope is negative. For C+OX2COX2 the gas amount is unchanged (slope nearly zero), and the metal oxide lines slope upwards because gas is consumed.