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How many structural isomers does the alkane have? Count structural isomers only (no stereoisomers).

  1. A3
  2. B4
  3. C5
  4. D6

Answer: C

Write the carbon skeletons: hexane, 2-methylpentane, 3-methylpentane, 2,2-dimethylbutane and 2,3-dimethylbutane. Enumeration gives 5 isomers (checked by computer enumeration).
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