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IUPAC Nomenclature and Structural Isomerism
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Structural isomerism: chain, position, functional, metamerism
JEE Advanced level
One or more correct options
Difficulty 3 of 3
nm165
Select the species with degree of unsaturation equal to 4.
A
spiro[4.4]nona-1,6-diene,
C
X
9
H
X
12
B
toluene,
C
X
7
H
X
8
C
benzaldehyde,
C
X
7
H
X
6
O
D
1-chloronaphthalene,
C
X
10
H
X
7
Cl
Answer: A, B
DU = (2C + 2 - H - X)/2: toluene (14 + 2 - 8)/2 = 4; the spirodiene (18 + 2 - 12)/2 = 4 (two rings plus two C=C); benzaldehyde (14 + 2 - 6)/2 = 5; 1-chloronaphthalene (20 + 2 - 7 - 1)/2 = 7.
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