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JEE Advanced levelSingle correct optionDifficulty 3 of 3nm043

Lowest locants are decided at the first point of difference, not by the sum of the locants. What is the IUPAC name of ?

  1. A2,6,6-trimethyloctane
  2. B3,3,7-trimethyloctane
  3. C3,7,7-trimethyloctane
  4. D2,2,6-trimethyloctane

Answer: A

The longest chain has eight carbons. Numbering from the left gives the locant set {2,6,6} and from the right {3,3,7}. The sums are 14 and 13, but the rule compares the sets term by term at the first point of difference: 2 < 3, so {2,6,6} is lower. The name is 2,6,6-trimethyloctane.
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