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JEE Main levelOne or more correct optionsDifficulty 2 of 3nm040

Each statement gives a structure and a proposed IUPAC name. Which of the following is/are correct?

  1. A is 2,2-dimethylbutane.
  2. B is 4-methylhexane.
  3. C is 3-methylpentane.
  4. D is 2,3-dimethylbutane.

Answer: A, C

3-Methylpentane is correct (five-carbon chain, methyl on C3). 2,2-Dimethylbutane is correct. The structure CH3-CH(CH3)-CH(CH3)-CH2-CH3 has a five-carbon longest chain, so it is 2,3-dimethylpentane and not 2,3-dimethylbutane. CH3-CH2-CH2-CH(CH3)-CH2-CH3 must be numbered from the right-hand end so that the methyl gets 3, giving 3-methylhexane, not 4-methylhexane.
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