JEE Main levelOne or more correct optionsDifficulty 2 of 3ie196
Equal volumes of AgNOX3 and NaCl solutions are mixed. With Ksp(AgCl)=1.8×10−10, in which cases does a precipitate form?
ABoth solutions 1.0×10−5M
BBoth solutions 1.0×10−4M
CBoth solutions 2.0×10−5M
DBoth solutions 3.0×10−5M
Answer: B, D
Mixing equal volumes halves each concentration. Ionic products are 2.5×10−11, 2.5×10−9, 1.0×10−10 and 2.25×10−10 respectively. Precipitation requires the product to exceed 1.8×10−10, which holds only for the second and fourth cases.