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Ionic Equilibrium I
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Buffer solutions and Henderson equation
JEE Advanced level
Numerical answer
Difficulty 3 of 3
ie156
150 mL of 0.20 M HA (
K
a
=
2.0
×
1
0
−
5
) is mixed with 100 mL of 0.10 M NaOH. Using
lo
g
2
=
0.301
, find the pH to two decimals.
Numerical answer type, tolerance 0.01.
Answer: 4.3979
HA = 30 - 10 = 20 mmol; A
−
= 10 mmol.
p
K
a
=
5
−
0.301
=
4.699
. pH =
4.699
+
lo
g
(
10/20
)
=
4.699
−
0.301
=
4.398
, i.e. 4.40.
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