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Ionic Equilibrium I
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Buffer solutions and Henderson equation
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Difficulty 2 of 3
ie133
60 mL of 0.10 M
NH
X
3
is mixed with 20 mL of 0.10 M HCl. Given
p
K
b
=
4.74
,
lo
g
2
=
0.301
,
p
K
w
=
14
, the pH is
A
4.44
B
9.26
C
10.26
D
9.56
Answer: D
NH
X
3
= 6 mmol, HCl = 2 mmol. After reaction
NH
X
3
= 4 mmol,
NH
X
4
X
+
= 2 mmol. pOH =
4.74
+
lo
g
(
2/4
)
=
4.439
; pH =
14
−
4.439
=
9.56
.
Practice Ionic Equilibrium I
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