JEE Advanced levelSingle correct optionDifficulty 3 of 3ie040
10mL of HCl of pH 6 is diluted to 100mL at 298 K. Taking water ionisation into account, the pH of the dilute solution is
A7.00
B6.70
C7.30
D6.79
Answer: D
Acid after dilution: C=10−7M. Then [HX+]=C+Kw/[HX+] gives [HX+]2−10−7[HX+]−10−14=0, so [HX+]=1.62×10−7M and pH=6.79. Simple addition (2×10−7) would give 6.70, which is wrong.