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JEE Main levelOne or more correct optionsDifficulty 2 of 3ia102

A solution is in and in (). Assume volume changes on adding solids or gas are negligible. Select the correct statement(s).

  1. AThe pH of the solution is 4.74
  2. BAfter adding of solid per litre, the pH becomes 4.83
  3. COn diluting tenfold with water, the pH rises to 5.74
  4. DAfter adding of per litre, the pH is 4.74

Answer: A, B

. Adding mol : acid , salt , so pH . A buffer's pH depends on the ratio, so tenfold dilution leaves it near 4.74 (the 5.74 claim is false). Adding mol converts all acetate to acetic acid (about ), giving pH near 2.72, not 4.74.
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