JEE Advanced levelSingle correct optionDifficulty 3 of 3ia015
0.10 M solutions of the sodium salts NaA and NaB of two weak acids HA and HB have pH 9.00 and 10.00 respectively at 298 K. The ratio Ka(HA)/Ka(HB) is
A0.01
B10
C0.1
D100
Answer: D
Kh=[OHX−]2/c. For NaA, [OHX−]=10−5 so Kh=1e−09; for NaB, [OHX−]=10−4 so Kh=1e−07. Since Ka=Kw/Kh, Ka(HA)/Ka(HB)=Kh(B)/Kh(A)=100. The ratio of [OH-] alone (10) is not the answer because Kh depends on the square.