JEE Main levelSingle correct optionDifficulty 2 of 3ig021
10mL of a gaseous hydrocarbon requires 25mL of OX2 for complete combustion and produces 20mL of COX2 (all volumes at the same temperature and pressure, water as liquid). The hydrocarbon is
ACX2HX6
BCX2HX4
CCX2HX2
DCX3HX8
Answer: C
CXxHXy+(x+4y)OX2xCOX2+(2y)HX2O(l). By Avogadro's law volume ratios equal mole ratios. x=20/10=2. x+y/4=25/10=2.5, so y/4=0.5 and y=2. The hydrocarbon is CX2HX2.