JEE Advanced levelNumerical answerDifficulty 3 of 3ig043
An equimolar mixture of He (molar mass 4) and CHX4 (molar mass 16) effuses through a pinhole. In the initial stage, when the composition inside has not changed appreciably, 1.00mmol of gas has effused in total. The amount of He in this effused gas in mmol (two decimals) is
Numerical answer type, answer in mmol, tolerance 0.01.
Answer: 0.67 mmol
Effusion rate of each gas ∝pi/Mi; with equal partial pressures, nCHX4nHe=416=2. So the effused gas is 2/3 He: 1.00×32=0.667≈0.67mmol.